(R)-(+)-3,5-Dinitro-N-(1-phenylethyl)benzothioamide
نویسندگان
چکیده
(R)-(+)-3,5-dinitro-N-(1-phenylethyl)benzothioamide 1 is a potential chiral solvating agent (CSA) for the spectral resolution of enantiomers via 1H NMR spectroscopy. The single enantiomer was synthesized from commercially available (R)-(+)-a-methylbenzylamine 2 in two steps with 85% yield.
منابع مشابه
2,4-Dinitro-1-phenoxybenzene
The title compound, C(12)H(8)N(2)O(5), was obtained by the reaction of 1-chloro-2,4-dinitro-benzene and phenol in the presence of potassium carbonate. The nitro-substituted benzene ring lies on a mirror plane, with one NO(2) group in the same plane and the other disordered across this plane. The phenoxy-benzene unit is placed perpendicular to this mirror, resulting in an exact orthogonal relati...
متن کامل2,4-Dinitro-1-naphthol
In the title compound, C(10)H(6)N(2)O(5), the two fused rings are almost co-planar, with an r.m.s. deviation of 0.0163 Å. The nitro groups are oriented at dihedral angles of 2.62 (11) and 44.69 (11)° with respect to the plane of the parent fused rings. Intra-molecular O-H⋯O and C-H⋯O hydrogen bonds complete S(6) ring motifs. In the crystal, mol-ecules are linked into chains along [101] by inter...
متن کاملDichlorido[(R,R)-N 1,N 1,N 2-tribenzylcyclohexane-1,2-diamine-κ2 N 1,N 2]copper(II)
In the title compound, [CuCl(2)(C(27)H(32)N(2))], which bears a chiral diamine ligand, viz (R,R)-N,N,N''- tribenzyl-cyclo-hexane-1,2-diamine, the Cu(II) ion is ligated by two N and two Cl atoms in a distorted square-planar geometry. The coordination of the ligands to the Cu(II) ion results in the formation of a five-membered heterocyclic ring and a chiral center at the monosubstituted nitro-gen...
متن کامل3,5-Dinitro-N-(4-nitrophenyl)benzamide
In the title mol-ecule, C(13)H(8)N(4)O(7), the amide fragment has an anti configuration. The mean planes of the two benzene rings form a dihedral angle of 7.78 (4)°. The mean planes of the three nitro groups are twisted by 6.82 (3), 5.01 (4) and 18.94 (7)° with respect to the benzene rings to which they are attached. In the crystal, mol-ecules are linked by weak inter-molecular N-H⋯O hydrogen b...
متن کامل(3,5-Dinitro-1,3,5-triazinan-1-yl)methanone
In the title compound, C(5)H(9)N(5)O(5), prepared from hexa-mine by acetyl-ation and nitration, the triazine ring adopts a chair conformation with all three substituent groups lying on the same side of the ring.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Molbank
سال: 2023
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1650